[keithlfrost]

This is a very sensible confusion. The forms of macroscopic averaging functions which are useful and valid cannot be made up arbitrarily, but are determined by the microscopic physical laws of the system. There is a reason that the law of increase of entropy is the second law of classical thermodynamics, with conservation of energy being the first law. To state it explicitly: energy is a globally conserved quantity, which can be freely exchanged among the interacting microscopic parts of systems. So we can bring a test system (called a thermometer) into interaction with our system under study, (indirectly) observe the average energy per degree of freedom of the thermometer, and call that observation the temperature of the system under study. Similarly, it is a known physical phenomenon that a gas confined to a container will exert a steady average outward force per normal unit area on the walls of the container; we have ways to measure this force, and we call it pressure. And so on, and on: every useful macroscopic averaging function is a relatively stable, measurable quantity which is determined by the physics of the systems under study. If we discovered some new measurement technique tomorrow which enabled us to measure the "quintessence" of physical systems, and this measurement was stable and reproducible, and could be meaningfully aggregated from the microscopic parts of the system and measured on the macroscopic scale, our definition of entropy would change, to account for "quintessence".