[maxiepoo]

Basic results that are useful on a day-to-day basis: 1. Yoneda's Lemma, and the corollary that objects defined by universal property are unique up to unique isomorphism 2. Right adjoints preserve limits and more generally, Kan extensions

The "big" theorem of basic category theory is probably the adjoint functor theorems which, once you realize that so many constructions in math are adjoint functors, gives very useful technical conditions to construct such an adjoint (ctrl-s for "applications" here for examples: https://math.stackexchange.com/questions/844131/adjoint-func...).

The most delightful surprising results to me come from categorical logic because that is what I am most familiar with. Here is one: any elementary topos is a model of intuitionistic higher-order logic, and also extensional dependent type theory. This vastly expands the domain of applications of logic if you are used to thinking only in terms of set-theoretic models. It also gives us applications of constructivism that are entirely independent from any philosophical debate about the nature of truth. This means that you can take many mathematical fields such as differential geometry, algebraic geometry, topology, as embodied in some category C, embed them into a sheaf topos and then use intuitionistic logic to do constructions and theorems in this area that are vastly simpler than the usual formulations. For instance you can do this with differential geometry and get an intuitionistic logic where you can work explicitly with infinitesimal numbers to calculate derivatives in a completely rigorous fashion. Ingo Blechschmidt has written some expository material in this vein (his main work being in using this in algebraic geometry): https://arxiv.org/abs/2204.00948

On the "surprising" side, I think the most surprising things for me where seeing how existing mathematical structures were examples of generalized categories: metric spaces are a kind of enriched category and topological spaces are generalized multicategories for the ultrafilter monad.