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Garbage In, Toxics Out

49 points| schlowmo | 2 years ago |theintercept.com

23 comments

order

fuoqi|2 years ago

The problem is with trying to "recycle" garbage plastic. Plastic is mostly carbon, oxygen, and hydrogen. Properly burning it using high-temperature (900+°C) pyrolysis converts most of plastic into water and carbon dioxide. There are some issues with sulfides and nitrogen oxides, but scrubbing those is a familiar problem for the industry. Remaining ash is relatively inert and can be used as a filler in various applications. Releasing carbon dioxide is not great, but it's much safer biologically than polluting environment and oceans with microplastics and total volume is relatively small compared to other emission sources.

Retric|2 years ago

I don’t see how sending plastics to a dump is going to result in ocean micro plastics. Environmentally you’re inefficiently generating energy from trash and reducing landfill size from bring trash vs failing to sequester the carbon in the trash and releasing some air pollution. I doubt pyrolysis is a net gain.

Properly constructed and operated landfills are a small source of methane, but otherwise quite benign.

mrkeen|2 years ago

> Properly burning it using high-temperature (900+°C) pyrolysis converts most of plastic into water and carbon dioxide.

I'm a little confused. Isn't pyrolysis what the company said they were doing?

Do they know what pyrolysis is, and are simply lying about doing it, or is pyrolysis a myth?

coldcode|2 years ago

I haven't been a chemist in more than 40 years, but even I know that pyrolysis of plastics makes a horrible toxic soup. There is no way to recycle many plastics in this way, the chemistry to reuse this resultant material doesn't exist. All it does is reduce the volume of material, which you then have to put somewhere. Also, the volatiles you generate have to go somewhere, and I highly doubt you want to breath them. You may as well live next to a battery recyling plant that uses coal for energy and raises pigs.

forgetfreeman|2 years ago

Fun little bit of trivia about the part of the world where this plant is located: the eastern 3rd of the state is blanketed in a thin film of aerosolized pig shit, so you're closer to the current state of play than maybe you thought.

CptFribble|2 years ago

Why are we still not talking about plasma gasification?

https://en.wikipedia.org/wiki/Plasma_gasification

As far as I can tell, the only real "disadvantages" if you can call them that, are:

1. more expensive than throwing the garbage in a big pile somewhere

2. need to clean it from time to time

3. not necessarily a profitable business

Other than that, it can handle just about anything that's not radioactive, can be designed to produce 0 toxic byproducts, and can run at or at least only slightly below energy neutral. Plasma gasifiers can also consume a huge amount of garbage for their size, so much so that the US Navy is starting to put them on the latest generation of aircraft carriers.

Not building out more gasifiers seems to me a failure of the free market. Because it's hard to make it profitable, no one is doing it - when really we should just be building one or two near every major city and funneling all our garbage there.

In theory, we could build out enough to start working through all the landfills too.

thmsths|2 years ago

I am glad you shared that link. I always wondered if we could just use plasma to get rid of waste. I figured it would be technically possible but prohibitively expensive, so I am happy to see the economics work out in some use cases. Skimming through the article, they mention that the plant needs lots of maintenance and frequent downtime, I am not sure how that would work out with the navy's high availability expectations for the carrier fleet.

jwx48|2 years ago

I've pretty much given up trying to recycle plastic, and instead throw it in the trash. It's toxic to make (I think?), contaminates food and water when you heat it, and--apparently--can not be recycled safely or efficiently. I realize I can't remove it from life entirely, but I'm actively avoiding it where I can and replacing it as opportunity permits.

nerdponx|2 years ago

I've heard it said that plastic is better off sequestered in landfills than recycled, to reduce the amount of microplastics getting into the environment.

snakeyjake|2 years ago

>I realize I can't remove it from life entirely, but I'm actively avoiding it where I can and replacing it as opportunity permits.

I realized this as well and have practically eliminated single-use plastics from my life except for those being those needed for health and safety reasons, like the blister packs that some medicines come in or bottles holding household chemicals.

Even with household chemicals, a strategy to minimize plastic use is to buy high-quality commercial applicators that can be reused for years and then purchase the product in bulk or concentrated form.

It isn't as easy as it should be, but at the same time it isn't difficult. It just requires time and effort.

When I discovered that bar shampoos and soaps that come in cardboard boxes contain the same ingredients as their liquid counterparts, and were less expensive because you weren't paying to transport water or mold a plastic bottle, it started a landslide of plastic avoidance.

dr_leviathan|2 years ago

I have been wondering for years why solar powered pyrolysis wasn't being used to recycle plastics. I thought it could reduce ALL plastics to an oil soup kinda like crude, which could then easily be separated by a distillery into various useful hydrocarbon oils for making new plastics/fuels. However now I'm starting to understand: the resulting soup is more toxic than crude and is difficult/expensive to distill, while the volatile byproducts that don't condense are another toxic liability. Bummer.

nerdponx|2 years ago

As suspected by many. But we should be grateful for actual reporting on it.

Was this not a problem with the older model of separated recycling (glass, plastic, and paper in separate bins), with plastic limited to numbers 1 and 2 only?

I'm also curious about if plasma gasification is a better option for plastics than whatever this process is.

sydbarrett74|2 years ago

Since the transition to electric vehicles will take decades (and some, like aircraft, may never fully make the switch), perhaps the synfuel generated from this pyrolysis can substitute for virgin petroleum. It could help make many parts of the world more energy-independent and less obligated to rely on the Middle East for oil.

The oil to make the original plastics has already been extracted, so it would be a carbon-neutral solution for the most part, especially if some of the plastics are burned to drive the process.

THe ultimate solution, though, is to lessen our dependence on plastic (Reduce), and completely eliminate single-use (Reuse).

flashback2199|2 years ago

I wonder how they make money. This sounds like grifters living off of government grants. I wonder how widespread the problem is of grifters taking government grants for fake green projects. Perhaps the country made the right move by not doing a green new deal after all. It looks like paying grifters to do science doesn't work very well.

nebula8804|2 years ago

So what if a few projects take money and go nowhere. GND was an infrastructure bill for the most part. The country's infrastructure is crumbling so might as well invest in new green infrastructure while employing the people who have been abandoned when all the factories closed down. (The situation in 2018/2019 when this bill was proposed was different than post-pandemic decoupling from China).

The legacy of GND is that it helped influence the Inflation Reduction Act so we sort of got to an extremely watered down version of what the original vision was.

projektfu|2 years ago

If you call out the problem generally you get denounced as part of the problem. Consider the reaction to "Planet of the Humans". There was a PR full court press from all the environmental groups to try to prevent people from watching it by attacking the messenger and focusing on trivial things while avoiding the discussion about the message.

It's just one example. I'm kind of bitter about the lack of attention to the effectiveness of the green tech movement and actually focusing on reduction of resource use.

mrkeen|2 years ago

I doubt cleaning up everyone's mess will ever be profitable.

And no doubt having the government pay private industry invites grifters.

I think a proper solution will necessarily involve going further left, i.e. government-employed workers. People who can't pocket the difference by cutting corners.

pstuart|2 years ago

This is so disappointing (but not surprising).

Many years ago there was a lot of press about a company call Changing World Technologies (https://en.wikipedia.org/wiki/Changing_World_Technologies) that touted how they could use pyrolysis to convert any hydrocarbon feedstock into fuel (garbage, sewage, etc).

It was going to be cost competitive and clean. Turned out to be not so much when their pilot plant processing turkey remnants stank up the town and shut them down.

The technology seems to be valuable, but it looks like capturing and containing emmissions is still not cost effective so they just dump it.