It's kinda a complicated question. Cherenkov radiation can be produced in any medium that has index of refraction greater than 1, that's what allows the charged particle radiation to go faster than the light it produces, which ultimate is what causes the Cherenkov light. The process is not reliant on the specific molecular/chemical/whatever properties of the medium, only dependent on the index of refraction. But, the index of refraction in turn comes from polarizabilty and magnetic susceptibility of the medium. Those factors depend on both what atoms & molecules exist in the medium, but also the structure of those molecules. For example, ice and water have the some chemical composition, but slightly different indices of refraction.
SiempreViernes|2 years ago
0PingWithJesus|2 years ago
Although, one further caveat, changing a materials absorption spectrum will also change it's refractive index as a function of wavelength, which will in turn effect how much Cherenkov light is emitted at each wavelength. So the situation is more complicated still.