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kken | 1 year ago
But you are complety right, the oxidation properties of Si are really fortunate and ICs would have taken decades longer if it were not for that. SiO2 is really the unsung hero of the silicon age.
- SiO2 has a high bandgap and a very good insulator.
- It is quite inert to many chemical and gasses. (e.g. germanium oxide is soluble in water, which is a headache)
- It can easily be grown on stoiciometric form by oxidizing silicon and will form an abrupt interface to Si.
- The formation proceeds by diffusion of oxygen to the Si interface. This is in contrast to other metal oxides, where the metal will diffuse to the surface and create a nonstoiciometric mixture.
There is no other semiconductor that forms as good an oxide. Very few metals form insulating oxides on their surface, one notable exception is Aluminum.
Edit: The famous paper that describes the SiO2 formation kinetics was actually co-authored by Andy Grove, from intel CEO fame.
stavros|1 year ago
arcanemachiner|1 year ago
Then I realized that if the products for building roads weren't around, then we wouldn't have had those roads in the first place, and I wouldn't have been reflecting on how lucky we were to have all this stuff.
namaria|1 year ago
kken|1 year ago
Not even mentioned yet:
- Excellent mechanical properties of the single crystal (think MEMS, or wafers that don't break all the time)
- Piezoresistive properties can be used to measure strain (also quite unique due to silicon band structure)
- Optical properties perfectly suited to detect visible light (think detectors, image sensors). Good combination of band gap and carrier lifetime to build solar cells.
eternauta3k|1 year ago
amelius|1 year ago
https://en.wikipedia.org/wiki/Optical_computing
layer8|1 year ago