It's the biggest solid piece of shell in English. Like the stuff over a crabs pincers is still shell but only the stuff that surrounds the main body is the carapace. Often used as an analogy for other sorts of armor, like a knights breastplate being his carapace or a tank's hull armor.
Carapace is rarely used outside a zoological context, but people may be more familiar with the derived word "scarab", being a beetle with a notable shell. It is unfortunately unrelated to the delicious dish carpaccio, which is named after a man.
I suspected Brandon Sanderson made it up for his Mistborn series until hearing it in Project Hail Mary also. This is actually why I clicked the thread: was curious if anyone would make the reference!
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