[pdm55]

The development of the lithium-ion battery is an example of how scientific discovery does not have a straight-line trajectory.

How We Got the Lithium-ion Battery

"One notable thing about the evolution of the lithium-ion battery is how hard it is to predict the trajectory of research, and how important it is to allow researchers the flexibility to pursue what they feel is promising. Whittingham stumbled across an intercalation-based battery when researching fast-ion transport through a solid electrolyte, an entirely different phenomenon. And his invention of the first lithium-ion battery cathodes was the result of a serendipitous discovery during work on superconductors. Thackeray discovered the manganese oxide cathode at Oxford ... for a year’s sabbatical so he could pursue the battery ideas he found promising. Early research on a graphite-based anode, performed by Rachid Yazami, was originally aimed at discovering a graphite-based cathode, not an anode, and Akira Yoshino’s battery efforts at Asahi Chemical were pursued in spite of the fact that company thought very little of the battery market, and only bore fruit because the company didn’t actively try and stop him. Likewise, the discovery of ethylene carbonate as an electrolyte that would allow graphite to be used as an anode was an accidental discovery by Moli Energy.

This sort of trajectory, of course, makes it hard to capture the value of research, or to have anything like a reliable, predictable path by which scientific research gets turned into marketable products. Exxon’s efforts to develop a practical rechargeable battery ultimately failed, though its research would spawn a successful battery in the fullness of time."

Source: https://www.construction-physics.com/p/how-we-got-the-lithiu...