I prefer Mercurial. It's easier to teach to non-programmers and it has a less confusing cli. Git has a terrible mess of cli options. I have also used Fossil and that is very nicely designed. Played a bit with bzr and darcs in the past. For many users Mercurial or Fossil would be the better tool for them than Git. Also checkout EasyMercurial, it's a suburb GUI for Mercurial.
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