[listeria]

If you look at the solar radiation spectrum chart in the section "Why isn’t the sky violet?", you can see that sunlight is not evenly distributed along the visible spectrum--it emit more blue than red, and at sea level it's closer to evenly distributed. So the light that reaches the clouds is still mostly white light.

[joveian]

I think it may also relate to chromatic adaptation. To be white it doesn't need to be any exact absolute color just the color our brain sets our white point to.

Not answering this question but I found an interesting short paper about how at sunset and sunrise the color gamut of shadows doesn't fully overlap with the direct illumination color gamut due to the differences in the paths the light takes:

Hubel. 2000. The Perception of Color at Dawn and Dusk.

https://library.imaging.org/admin/apis/public/api/ist/websit...