[joveian]

I think it may also relate to chromatic adaptation. To be white it doesn't need to be any exact absolute color just the color our brain sets our white point to.

Not answering this question but I found an interesting short paper about how at sunset and sunrise the color gamut of shadows doesn't fully overlap with the direct illumination color gamut due to the differences in the paths the light takes:

Hubel. 2000. The Perception of Color at Dawn and Dusk.

https://library.imaging.org/admin/apis/public/api/ist/websit...